The aqueous chemistry of oxides /

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Hlavní autoři: Bunker, Bruce C. (Autor), Casey, William Howard, 1955- (Autor)
Typ dokumentu: Kniha
Jazyk:Angličtina
Vydáno: New York, NY : Oxford University Press, 2016
Vydání:First edition
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On-line přístup:Elektronická verze přístupná pouze pro studenty a pracovníky MU
Příbuzné jednotky:Tištěná verze:: Aqueous chemistry of oxides.
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100 1 |a Bunker, Bruce C.  |7 jo20221151706  |4 aut 
245 1 4 |a The aqueous chemistry of oxides /  |c Bruce C. Bunker and William H. Casey 
250 |a First edition 
264 1 |a New York, NY :  |b Oxford University Press,  |c 2016 
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505 0 |a Cover; Contents; Cover Art Figure Captions; Plates; PART ONE An Introduction to Oxides; 1. The Importance of Oxides and Oxide-Water Reactions; 1.1. Geochemical Importance; 1.2. The Technological Importance of Oxides; 1.3. The Physical Properties of Oxides; 1.4. The Chemical Properties of Oxides; 1.5. The Aqueous Chemistry of Oxides: A Road Map; 2. An Overview of Oxide Structures and Compositions; 2.1. Local Oxide Structures: The Oxide (O2-) Anion; 2.2. Predicting Oxygen-Bonding Configurations: An Introduction to the Formal-Charge Model; 2.3. Close-Packed Crystalline Lattices 
505 8 |a 2.4. Oxides Containing Octahedral Cations2.5. Oxides Containing Tetrahedral Cations; 2.6. Oxides Containing Both Octahedral and Tetrahedral Cations; 2.7. Engineered Oxide Nanostructures; PART TWO Fundamental Oxide Reactions in Aqueous Solutions; 3. The Structure and Properties of Water; 4. Solvated Ions in Water; 4.1. Introduction; 4.2. Solvated Anions; 4.3. Solvated Cations; 4.4. The Structure of Solvated Cations; 4.5. The Acid-Base Properties of the First Solvation Shell; 4.6. Using Formal Charge Models to Predict and Rationalize pKa Values; 4.7. An Introduction to Ligand-Exchange Reactions 
505 8 |a 4.8. The Thermodynamics of Ligand Exchange4.9. The Kinetics of Ligand-Exchange Reactions; 5. The Hydrolysis Products: Soluble Multi-cation Clusters; 5.1. Introduction; 5.2. Structures of the Hydrolysis Products; 5.3. The Occurrence of Hydrolysis Products: Reading Hydrolysis Diagrams; 5.4. Trends in Cation Hydrolysis; 5.5. Hydrolysis Diagrams as Predictors of Oxide Chemistry; 5.6. Speciation Diagrams Involving Foreign Ligands; 5.7. The Acid-Base Chemistry of Multi-Cation Hydrolysis Products; 5.8. Mechanisms for Reversible Condensation Reactions 
505 8 |a 5.9. Hydrolysis Product Stability: Dimer Reaction Pathways5.10. The Stability of Larger Hydrolysis Products; 5.11. The Polyoxometalates: Covalent Oxide Clusters; 6. The Chemistry of Extended Oxide Surfaces; 6.1. Introduction; 6.2. Ideal Oxide Surfaces in the Absence of Water; 6.3. Interactions between Pristine Surfaces and Water Molecules; 6.4. The Interface between Liquid Water and Oxide Surfaces; 6.5. Acid-Base Reactions on Oxide Surfaces in Liquid Water; 6.6. Ligand-Exchange Reactions Involving Water: Oxide Dissolution; 6.7. Reactions Involving Foreign Ligands 
505 8 |a PART THREE The Aqueous Synthesis and Processing of Oxides7. Nucleation and Growth of Solid Oxide and Hydroxide Phases; 7.1. Introduction; 7.2. Classic Nucleation Theory; 7.3. Chemical Control of Oxide Nucleation; 7.4. Classic Growth Theory; 8. The Colloidal Chemistry of Oxides; 8.1. Introduction; 8.2. Fundamental Colloidal Interactions; 8.3. The Chemical Origin of Surface Charge; 8.4. The Impact of Aggregation on the Properties of Colloidal Slurries; 8.5. Ceramic Processing: The Role of Organic Additives; 9. Bio-inspired Synthesis of Oxide Nanostructures; 9.1. Introduction 
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